She was on her way to a private view of a new collection by Mario Testino.
But by the looks of it, all eyes were to be on Kim Kardashian and her attention-grabbing outfit rather than the photography on display.
The 33-year-old was a knockout in a sheer-top that showed off her ample cleavage.
Her all-white ensemble was figure-hugging to say the least as she opted for a tight-fitting skirt.
The exhibition, Alta Moda, meaning 'high fashion' in Spanish, documents Peruvians in their vibrantly colored and ornately adorned traditional and festive dress from Cusco, one of the highest mountainous regions of Peru.
But it looks as though Kim - who was joined by her little sister Kendall Jenner - didn't get the memo as she turned up in white.
Kendall - a budding fashion model - would no doubt love the opportunity to work with esteemed photographer Mario Testino.
Meanwhile Kim's motormouth mother Kris Jenner recently let slip that she hopes Kim and Kanye will marry next year.
The couple - who have five-month-old daughter North together - got engaged last month after the rapper proposed at the AT&T Park baseball park in San Francisco in front of her family.
Kim's mother Kris is very excited about the nuptials but has no idea when they will happen, although she is hoping for a 2014 ceremony.
In an interview with Entertainment Tonight correspondent Cheryl Woodcock, Kris was asked if she knew when the wedding will take place, to which she replied: 'As soon as I know, I'm going to let you know. Hopefully, probably, next year.'
Kris also revealed Kim is yet to pick her bridal gown when quizzed by Cheryl, only answering: 'Not yet.'
Kris - who also acts as Kim's manager and oversees the affairs of her other daughters Khloe and Kourtney - recently revealed she will have no input in her daughter's wedding dress decision.
Instead, the 58-year-old star - who has separated from her husband Bruce Jenner - will let her 33-year-old daughter make all the decisions about her bridal gown by herself.
Kris said: '(She can wear) whatever she falls in love with. I think that's so specific to a bride. You can imagine what she might wear, but she's got to feel it and put it on and think, "This is the dress!"'
Meanwhile, as Kim and Kendall stepped out together - their other sister Kylie arrived at the Hunger Games: Catching Fire premiere alone.
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